全文获取类型
收费全文 | 581篇 |
免费 | 38篇 |
国内免费 | 17篇 |
专业分类
化学 | 436篇 |
晶体学 | 1篇 |
力学 | 38篇 |
数学 | 83篇 |
物理学 | 78篇 |
出版年
2023年 | 1篇 |
2022年 | 13篇 |
2021年 | 20篇 |
2020年 | 25篇 |
2019年 | 38篇 |
2018年 | 33篇 |
2017年 | 27篇 |
2016年 | 62篇 |
2015年 | 35篇 |
2014年 | 34篇 |
2013年 | 95篇 |
2012年 | 49篇 |
2011年 | 41篇 |
2010年 | 39篇 |
2009年 | 24篇 |
2008年 | 22篇 |
2007年 | 28篇 |
2006年 | 7篇 |
2005年 | 11篇 |
2004年 | 7篇 |
2003年 | 7篇 |
2002年 | 6篇 |
2001年 | 2篇 |
2000年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1980年 | 1篇 |
排序方式: 共有636条查询结果,搜索用时 62 毫秒
631.
Javad Azizian Farhad Hatamjafari Ali Reza Karimi 《Journal of heterocyclic chemistry》2006,43(5):1349-1352
A series of some new spiro‐1,4‐dihydropyridine derivatives have been synthesized in good yields in a four component, and solvent‐free process by condensation of isatins, primary amines, ethyl cyanoacetate and cyclohexanone on solid support montmorillonite K10 相似文献
632.
Javad Azizian Ali A. Mohammadi Ebrahim Soleimani Ali R. Karimi Mohammad R. Mohammadizadeh 《Journal of heterocyclic chemistry》2006,43(1):187-190
A mild and stereoselective three‐component one‐step synthesis of cis‐isoquinolonic acid using silica sulfuric acid as a heterogeneous catalyst from an aldehyde, amine and homophthalic anhydride in acetonitrile is described. This new method produces pure products in high yields (81‐91%). 相似文献
633.
Javad Safari Shiva Dehghan Khalili Mehran Rezaei Sayed Hossein Banitaba Fereshteh Meshkani 《Monatshefte für Chemie / Chemical Monthly》2010,122(3):1339-1345
Abstract
Nanocrystalline magnesium oxide with high specific surface area has been used as a novel and efficient catalyst for an improved and rapid synthesis of biologically active 2,4,5-trisubstituted imidazoles, by three-component, one-pot condensation of 1,2-diketones and aryl aldehydes, in excellent yields under solvent-free and conventional heating conditions. The method has several advantages, for example excellent yields, shorter reaction time, and use of a non-toxic and recyclable catalyst. 相似文献634.
Javad S. Z. Sabounchei Brian T. Heaton Jonathan A. Iggo Chacko Jacob Ivan S. Podkorytov 《Journal of Cluster Science》2001,12(1):339-348
A complete NMR study involving both 1D and 2D 13C-{103Rh} and 31P-{103Rh} HMQC measurements, on [Rh6C(CO)14(PPh3)]2- are reported and discussed, together with the multiple Rh quantum effects found for resonances associated with edge- and face-bridging CO's. As found in [Rh6C(CO)15]2-, the carbonyl ligands in [Rh6C(CO)14(PPh3)]2- undergo CO-intermolecular exchange with 13CO at different rates; for the edge-bridging CO's, the lower the value of 1J(Rh–CO), the faster the rate of intermolecular exchange with 13CO. 相似文献
635.
Javad Azizian Mohammad R. Mohammadizadeh Ali A. Mohammadi Ali R. Karimi Fatemeh Teimouri 《Heteroatom Chemistry》2007,18(1):16-18
A novel one‐pot procedure for preparation of some new condensed pyrido[2,3‐d]pyrimidine(1H,3H)‐2,4‐diones based on condensation of ninhydrin, alkyl cyanoacetate, and 6‐aminouracil derivatives has been reported. The reactions were carried out in refluxed ethanol and were completed in less than 2 h. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:16–18, 2007; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20242 相似文献
636.
Marilyn M. Olmstead Javad J. Sahbari 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(12):o719-o720
The oxime of acetamide, viz. N‐hydroxyethanimidamide, C2H6N2O, has a complex hydrogen‐bonding arrangement in its crystal structure, featuring one strong O—H⋯N hydrogen bond together with weaker hydrogen bonding involving the amide groups. Conjugation effects lead to atypical distances and angles. 相似文献